Hort. Sci. (Prague), 2003, 30(2):73-79 | DOI: 10.17221/3818-HORTSCI

The essential oil content in caraway species (Carum carvi L.)

J. Sedláková, B. Kocourková, L. Lojková, V. Kubáň
1 Mendel University of Agriculture and Forestry, Department of Chemistry and Biochemistry, Brno, Czech Republic
2 Mendel University of Agriculture and Forestry, Department of Plant Science and Breeding, Brno, Czech Republic

Caraway fruits contain 1-6% of essential oils consisting of about 30 compounds, from which carvone and limonene account form the main portion, about 95%. To evaluate the quality of various caraway cultivars, the amounts of essential oils and the carvone/limonene ratio were measured. The most common method of essential oil evaluation is steam distillation in accordance with Standard ČSN 58 0110, but an alternative method - supercritical fluid extraction (SFE) - was also investigated in this paper. Ground caraway fruits were extracted under different SFE conditions (pressure, temperature, use of modifiers). Released compounds (carvone and limonene) were quantified by GC.

Keywords: supercritical fluid extraction (SFE); caraway seeds; carvone; limonene; gas chromatography (GC); cultivars

Published: June 30, 2003  Show citation

ACS AIP APA ASA Harvard Chicago Chicago Notes IEEE ISO690 MLA NLM Turabian Vancouver
Sedláková J, Kocourková B, Lojková L, Kubáň V. The essential oil content in caraway species (Carum carvi L.). Hort. Sci. (Prague). 2003;30(2):73-79. doi: 10.17221/3818-HORTSCI.
Download citation

References

  1. BOUNOSHITA M., HIBI K., NAKAMURA H., 1993. Determination of enantiomer rations of d,l-carvone in supercritical fluid extracts from caraway seeds and spearmint leaves by high-performance liquid chromatography with polarimetric and ultraviolet spectrophotometric detection. Anal. Sci., 9: 425-428. Go to original source...
  2. BOUWMEESTER H.J., DAVIES J.A.R., TOXOPEUS H., 1995. Enantiomeric composition of carvone, limonene, and carveols in seeds of dill and annual and biennial caraway varieties. J. Agric. Food Chem., 43: 3057-3064. Go to original source...
  3. ENGELHARDT H., GROSS A., 1988. On-line extraction and separation by supercritical fluid chromatography with packed columns. J. High Resolut. Chromatogr. Commun., 11: 38-42. Go to original source...
  4. CHURÁČEK J., 1992. Identifikace a stanovení cizorodých, toxikologicky významných organických látek v materiálech a prostředí. [Skripta licenčního studia II.] Pardubice, VŠCHT: 15.
  5. KALLIO H., KERROLA K., ALHONMAKI P., 1994. Carvone and limonene in caraway fruits (Carum carvi L.) analyzed by supercritical carbon dioxide extraction - gas chromatography. J. Agric. Food Chem., 42: 2478-2485. Go to original source...
  6. KAMENÍK J., 1996. Perspektivy uplatnění kmínu v zemědělství v ČR. [Sborník.] Brno, MZLU: 8-10.
  7. KOCOURKOVÁ B., SEDLÁKOVÁ J., HOLUBOVÁ V., 1999. Morfologické a kvalitativní znaky registrovaných odrůd. [Sborník.] Brno, MZLU: 34-41.
  8. KOVAR K.A., BOCK E., 1983. Quantitative analysis of a mixture of extracts of drugs from volatile oils by high performance liquid chromatography. J. Chromatogr., 262: 285-291. Go to original source...
  9. MANI V., WIOOLEY C., 1995. Solid phase microextraction and chiral gas chromatography separation. LC-GC, 13, 734-736, 738, 740.
  10. MHEEN H.J., 1994. Comparison and development (during the ripening phase) of the seed and carvone yield of (summer) caraway and dill. Verslag Proefstation voor de Akkerbouw en de Groenteteelt in de Vollegrond, 184: 105.
  11. MINAŘÍK J., 2001. Kmín kořenný. Úroda, 9: 10-11.
  12. MOSSA J.B., EL-OBEID H.A., HASSAN M.M.A., 1980. Proton magnetic assay of essential oils. IV. Assay of carvone in caraway and sill oils. Spectrosc. Lett., 13: 49-57. Go to original source...
  13. ONDŘEJ M. et al., 1997. Biodiverzita, její uchování a využívání pro setrvalý rozvoj zemědělství a zabezpečení jeho funkcí. [Výroční zpráva projektu NAZV MZe ČR.] 13.
  14. ONDŘEJ M. et al., 1998. Biodiverzita, její uchování a využívání pro setrvalý rozvoj zemědělství a zabezpečení jeho funkcí. [Výroční zpráva projektu NAZV MZe ČR.] 15.
  15. SEDLÁKOVÁ J., 1997. Superkritická fluidní extrakce VIII. [Diplomová práce.] Pardubice, Univerzita Pardubice: 77.
  16. SEDLÁKOVÁ J., KUBÁŇ V., HOLUBOVÁ V., KOCOURKOVÁ B., 1998. Stanovení silic v kmínu. [Sborník.] Komorní Lhotka, 2 THETA: 120-126.
  17. SEIF EL DIN A.A., KORANY M.A., ABDEL SALAM N.A., 1983. Application of second derivate ultraviolet spectrometry. II. Determination of cinnamylaldehyde and carvone in volatille oils. Anal. Lett., 16: 891-901. Go to original source...
  18. ŠPALDON E. et al., 1986. Rostlinná výroba. Praha, SZN: 715.
  19. THIES W., 1984. HPLC of essential oils (lavender, pepermint, caraway). Fresenius J. Anal. Chem., 318: 249-250. Go to original source...

This is an open access article distributed under the terms of the Creative Commons Attribution-NonCommercial 4.0 International (CC BY NC 4.0), which permits non-comercial use, distribution, and reproduction in any medium, provided the original publication is properly cited. No use, distribution or reproduction is permitted which does not comply with these terms.